96-26-4/1,3-Dihydroxyacetone

Quick Details
Molecular Formula:C3H6O3
Molecular Weight:90.0788
Appearance:white powder
CasNo:96-26-4

  • Product Details

    CasNo:96-26-4

    Product Name:1,3-Dihydroxyacetone

    Molecular Formula:C3H6O3

    Appearance:white powder

    Purity:99%

    Buy Buy High Quality 1,3-Dihydroxyacetone 96-26-4 Low Price

    • Molecular Formula:C3H6O3
    • Molecular Weight:90.0788
    • Appearance/Colour:white powder 
    • Vapor Pressure:0.0358mmHg at 25°C 
    • Melting Point:75-80 °C 
    • Refractive Index:1.455 
    • Boiling Point:213.7 °C at 760 mmHg 
    • PKA:12.45±0.10(Predicted) 
    • Flash Point:97.3 °C 
    • PSA:57.53000 
    • Density:1.283 g/cm3 
    • LogP:-1.45990 

    1,3-Dihydroxyacetone(Cas 96-26-4) Usage

    Chemical Properties

    white powder

    Occurrence

    A derivative of naturally occurring starch

    Uses

    1,3-Dihydroxyacetone can be used as artificial tanning agent.

    Preparation

    Usually produced commercially from Bacillus macerans or Bacillus circulans fermentation of starch or starch hydrolysate

    Definition

    ChEBI: A ketotriose consisting of acetone bearing hydroxy substituents at positions 1 and 3. The simplest member of the class of ketoses and the parent of the class of glycerones.

    Taste threshold values

    Reported to have a taste threshold value lower than that of sucrose with a detection level of 3.9 to 27 ppm and a recognition level of 11 to 52 ppm.

    General Description

    Dihydroxyacetone (DHA) is a browning ingredient widely used in cosmetics such as sunless tanning formulations. It participates in a chemical staining reaction called Milliard reaction in which it reacts with the amino groups of proteins to result in a mixture of high molecular weight pigments.Pharmaceutical secondary standards for application in quality control, provide pharma laboratories and manufacturers with a convenient and cost-effective alternative to the preparation of in-house working standards.

    Safety Profile

    Mutation data reported. When heated to decompositionit emits acrid smoke and irritating vapors.

    Consumer Uses

    This substance is used in the following products: cosmetics and personal care products and perfumes and fragrances. Other release to the environment of this substance is likely to occur from: indoor use as processing aid and outdoor use as processing aid.

    InChI:InChI=1/C3H6O3/c4-1-3(6)2-5/h4-5H,1-2H2

    96-26-4 Relevant articles

    The selective oxidation of glycerol over metal-free photocatalysts: insights into the solvent effect on catalytic efficiency and product distribution

    Fan, Mingming,Haryonob, Agus,Jiang, Pingping,Leng, Yan,Yue, Chengguang,Zhang, Pingbo

    , p. 3385 - 3392 (2021/06/06)

    Selective oxidation of glycerol to high ...

    Earth-abundant manganese oxide nanoneedle as highly efficient electrocatalyst for selective glycerol electro-oxidation to dihydroxyacetone

    Chiang, Chia-Ying,Tran, Giang-Son,Vo, Truong-Giang

    , p. 139 - 148 (2021/10/07)

    In this study, earth-abundant manganese ...

    A proof of concept for cooperation from the quinone groups adjacent to N sites during the metal-free oxidation of glycerol by nitrogen-rich graphene oxide

    Barlocco, Ilaria,Dogra, Ashima,Gupta, Neeraj,Sharma, Vinit,Villa, Alberto

    supporting information, p. 19651 - 19654 (2021/11/12)

    Glycerol is a key by-product in biodiese...

    Assembly of platinum nanoparticles and single-atom bismuth for selective oxidation of glycerol

    Huang, Ning,Jiang, Dong,Jiang, Pingping,Leng, Yan,Lu, Yubing,Tian, Jinshu,Yue, Chenguang,Zhang, Pingbo,Zhang, Zihao

    supporting information, p. 25576 - 25584 (2021/12/07)

    Selective oxidation of the secondary hyd...

    96-26-4 Process route

    acetophenone
    98-86-2

    acetophenone

    glycerol
    56-81-5,25618-55-7,64333-26-2,8013-25-0

    glycerol

    dihydroxyacetone
    96-26-4,26776-70-5

    dihydroxyacetone

    1-Phenylethanol
    98-85-1,13323-81-4

    1-Phenylethanol

    Conditions
    Conditions Yield
    With [IrCl(COD)(C3H2N2(3,4,5-trimethoxybenzyl)(n-Bu))]; potassium hydroxide; at 120 ℃; for 7h; Inert atmosphere;
    80%
    With C40H50IrNP2; at 120 ℃; for 1h; chemoselective reaction; Inert atmosphere;
    8 %Chromat.
    6 %Chromat.
    acetophenone
    98-86-2

    acetophenone

    glycerol
    56-81-5,25618-55-7,64333-26-2,8013-25-0

    glycerol

    dihydroxyacetone
    96-26-4,26776-70-5

    dihydroxyacetone

    1-Phenylethanol
    98-85-1,13323-81-4

    1-Phenylethanol

    cis-(2-methyl-2-phenyl-[1,3]-dioxolane-4-yl)methanol

    cis-(2-methyl-2-phenyl-[1,3]-dioxolane-4-yl)methanol

    trans-(2-methyl-2-phenyl-[1,3]-dioxolane-4-yl)methanol

    trans-(2-methyl-2-phenyl-[1,3]-dioxolane-4-yl)methanol

    C<sub>11</sub>H<sub>14</sub>O<sub>3</sub>

    C11H14O3

    C<sub>11</sub>H<sub>14</sub>O<sub>3</sub>

    C11H14O3

    Conditions
    Conditions Yield
    With bis[dichloro(pentamethylcyclopentadienyl)iridium(III)]; at 40 ℃; for 1h; Molecular sieve;

    96-26-4 Upstream products

    • 110-86-1
      110-86-1

      pyridine

    • 56-82-6
      56-82-6

      Glyceraldehyde

    • 50-00-0
      50-00-0

      formaldehyd

    • 50-99-7
      50-99-7

      D-glucose

    96-26-4 Downstream products

    • 822-36-6
      822-36-6

      4-methyl-1H-imidazole

    • 78-98-8
      78-98-8

      2-oxopropanal

    • 75-07-0
      75-07-0

      acetaldehyde

    • 15719-64-9
      15719-64-9

      methylammonium carbonate


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